Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/85610
Title: Polyhalides as efficient and mild oxidants for oxidative carbene organocatalysis by radical processes
Authors: Wu, Xingxing
Zhang, Yuexia
Wang, Yuhuang
Ke, Jie
Jeret, Martin
Reddi, Rambabu N.
Yang, Song
Song, Bao-An
Chi, Robin Yonggui
Keywords: Science::Chemistry
Issue Date: 2017
Source: Wu, X., Zhang, Y., Wang, Y., Ke, J., Jeret, M., Reddi, R. N., Yang, S., Song, B. & Chi, R. Y. (2017). Polyhalides as efficient and mild oxidants for oxidative carbene organocatalysis by radical processes. Angewandte Chemie International Edition, 56(11), 2942-2946. https://dx.doi.org/10.1002/anie.201611692
Project: NRF-NRFI2016-06
MOE2013-T2-2-003
Journal: Angewandte Chemie International Edition
Abstract: Simple and inexpensive polyhalides (CCl4 and C2Cl6 ) have been found to be effective and versatile oxidants in removing electrons from Breslow intermediates under N-heterocyclic carbene (NHC) catalysis. This oxidative reaction involves multiple single-electron-transfer (SET) processes and several radical intermediates. The α, β, and γ-carbon atoms of aldehydes and enals could be readily functionalized. Given the low cost of the oxidants and the broad applicability of the reactions, this study is expected to greatly enhance the feasibility of oxidative NHC catalysis for large-scale applications. Also this new SET radical process with polyhalides as single-electron oxidants will open a new avenue in the development of NHC-catalyzed radical reactions.
URI: https://hdl.handle.net/10356/85610
http://hdl.handle.net/10220/43775
ISSN: 1433-7851
DOI: 10.1002/anie.201611692
Rights: This is the peer reviewed version of the following article: Wu, X., Zhang, Y., Wang, Y., Ke, J., Jeret, M., Reddi, R. N., Yang, S., Song, B. & Chi, R. Y. (2017). Polyhalides as efficient and mild oxidants for oxidative carbene organocatalysis by radical processes. Angewandte Chemie International Edition, 56(11), 2942-2946, which has been published in final form at https://doi.org/10.1002/anie.201611692. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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