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https://hdl.handle.net/10356/85730| Title: | Alkyl ethers as traceless hydride donors in brønsted acid catalyzed intramolecular hydrogen atom transfer | Authors: | Gandamana, Dhika Aditya Wang, Bin Tejo, Ciputra Bolte, Benoit Gagosz, Fabien Chiba, Shunsuke |
Keywords: | DRNTU::Science::Chemistry Hydrogen Atom Transfer Brønsted Acid |
Issue Date: | 2018 | Source: | Gandamana, D. A., Wang, B., Tejo, C., Bolte, B., Gagosz, F., & Chiba, S. (2018). Alkyl Ethers as Traceless Hydride Donors in Brønsted Acid Catalyzed Intramolecular Hydrogen Atom Transfer. Angewandte Chemie International Edition, 57(21), 6181-6185. doi:10.1002/anie.201801953 | Series/Report no.: | Angewandte Chemie International Edition | Abstract: | A new protocol for the deoxygenation of alcohols and the hydrogenation of alkenes under Brønsted acid catalysis has been developed. The method is based on the use of either a benzyl or isopropyl ether as a traceless hydrogen‐atom donor, and involves an intramolecular hydride transfer as a key step, which is achieved in a regio‐ and stereoselective manner. | URI: | https://hdl.handle.net/10356/85730 http://hdl.handle.net/10220/48237 |
ISSN: | 1433-7851 | DOI: | 10.1002/anie.201801953 | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the peer reviewed version of the following article: Gandamana, D. A., Wang, B., Tejo, C., Bolte, B., Gagosz, F., & Chiba, S. (2018). Alkyl Ethers as Traceless Hydride Donors in Brønsted Acid Catalyzed Intramolecular Hydrogen Atom Transfer. Angewandte Chemie International Edition, 57(21), 6181-6185., which has been published in final form at http://dx.doi.org/10.1002/anie.201801953. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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|---|---|---|---|---|
| Alkyl Ethers as Traceless Hydride Donors in Brønsted Acid Catalyzed Intramolecular Hydrogen Atom Transfer.pdf | 640.75 kB | Adobe PDF |  View/Open |
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