Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/86641
Title: Brønsted Base-Mediated Aziridination of 2-Alkyl-Substituted-1,3-Dicarbonyl Compounds and 2-Acyl-Substituted-1,4-Dicarbonyl Compounds by Iminoiodanes
Authors: Tejo, Ciputra
Tirtorahardjo, Davin
Day, David Philip
Ma, Dik-Lung
Leung, Chung-Hang
Chan, Philip Wai Hong
Keywords: Brønsted Base-mediated
Aziridination
Issue Date: 2017
Source: Tejo, C., Tirtorahardjo, D., Day, D. P., Ma, D.-L., Leung, C.-H., & Chan, P. W. H. (2017). Brønsted Base-Mediated Aziridination of 2-Alkyl-Substituted-1,3-Dicarbonyl Compounds and 2-Acyl-Substituted-1,4-Dicarbonyl Compounds by Iminoiodanes. Australian Journal of Chemistry, 70(4), 430-435.
Series/Report no.: Australian Journal of Chemistry
Abstract: The synthesis of α,α-diacylaziridines and α,α,β-triacylaziridines from reaction of 2-alkyl-substituted-1,3-dicarbonyl compounds and 2-acyl-substituted-1,4-dicarbonyl compounds with arylsulfonyliminoiodinanes (ArSO2N=IPh) under Brønsted base-mediated atmospheric conditions is described. The reaction mechanism is thought to involve the formal oxidation of the substrate followed by aziridination of the ensuing α,β-unsaturated intermediate by the hypervalent iodine(III) reagent.
URI: https://hdl.handle.net/10356/86641
http://hdl.handle.net/10220/44140
ISSN: 0004-9425
DOI: 10.1071/CH16580
Rights: © 2017 CSIRO Publishing. This is the author created version of a work that has been peer reviewed and accepted for publication by Australian Journal of Chemistry, CSIRO Publishing. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1071/CH16580].
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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