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Title: Crystalline boron-linked tetraaminoethylene radical cations
Authors: Su, Yuanting
Li, Yongxin
Ganguly, Rakesh
Kinjo, Rei
Keywords: Radical Cations
Issue Date: 2017
Source: Su, Y., Li, Y., Ganguly, R., & Kinjo, R. (2017). Crystalline boron-linked tetraaminoethylene radical cations. Chemical Science, 8(11), 7419-7423.
Series/Report no.: Chemical Science
Abstract: Single-electron oxidation of neutral boryl-linked tetraaminoethylene derivatives 4 led to the formation of radical cations 4˙+, which have been isolated and fully characterized. X-ray diffraction analysis, EPR spectroscopy, and computational studies revealed that the unpaired electron is delocalized over the B2N4C2 skeleton and the spin density mainly resides on the carbon and boron atoms.
ISSN: 2041-6520
DOI: 10.1039/C7SC03528D
Rights: © 2017 The Author(s) (published by Royal Society of Chemistry). This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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