Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/87048
Title: Rapid access to bicyclic δ-lactones via carbene-catalyzed activation and cascade reaction of unsaturated carboxylic esters
Authors: Fu, Zhenqian
Wu, Xingxing
Chi, Robin Yonggui
Keywords: Iridoid
Bicyclic Ring
Issue Date: 2016
Source: Fu, Z., Wu, X., & Chi, R. Y. (2016). Rapid access to bicyclic δ-lactones via carbene-catalyzed activation and cascade reaction of unsaturated carboxylic esters. Organic Chemistry Frontiers, 3(2), 145-149.
Series/Report no.: Organic Chemistry Frontiers
Abstract: Carboxylic esters are an excellent choice of substrates in organic synthesis. Here we demonstrate that carbene-catalyzed activation of α,β-unsaturated ester can be developed to synthesize sophisticated multi-cyclic molecules in a single step cascade process. The iridoid-type lactone products are obtained with high stereo-selectivities, and can readily undergo further transformations.
URI: https://hdl.handle.net/10356/87048
http://hdl.handle.net/10220/45223
ISSN: 2052-4110
DOI: 10.1039/C5QO00348B
Rights: © 2016 The Partner Organisations. This is the author created version of a work that has been peer reviewed and accepted for publication by Organic Chemistry Frontiers, The Partner Organisations. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1039/C5QO00348B].
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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