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Title: Resolving H(Cl, Br, I) capabilities of transforming solution hydrogen-bond and surface-stress
Authors: Zhang, Xi
Zhou, Yong
Gong, Yinyan
Huang, Yongli
Sun, Changqing
Keywords: Acid Solution
Surface Stress
Issue Date: 2017
Source: Zhang, X., Zhou, Y., Gong, Y., Huang, Y., & Sun, C. (2017). Resolving H(Cl, Br, I) capabilities of transforming solution hydrogen-bond and surface-stress. Chemical Physics Letters, 678, 233-240.
Series/Report no.: Chemical Physics Letters
Abstract: A combination of differential phonon spectrometrics (DPS) and DFT calculations verified the essentiality of H+ ↔ H+ point fragilization and X− polarization dictating the surface stress of HX (X = Cl, Br, I) solutions. H+ ↔ H+ repulsion breaks the network regularly; X− polarization shortens and stiffens the HO bonds but lengthens and softens the O:H nonbonds in its hydration shell. The X− capability of hydrogen bond and surface stress transformation follows the order of I > Br > Cl. Observations provide fresh insight into the acid solvation network dynamics. DPS resolves solute capabilities of transforming the bonds and surface stress.
ISSN: 0009-2614
DOI: 10.1016/j.cplett.2017.04.060
Rights: © 2017 Elsevier B.V. This is the author created version of a work that has been peer reviewed and accepted for publication by Chemical Physics Letters, Elsevier B.V. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [].
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:EEE Journal Articles

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