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Title: Asymmetric Conjugate Addition of Organoboron Reagents to Common Enones Using Copper Catalysts
Authors: Wu, Chunlin
Yue, Guizhou
Nielsen, Christian Duc-Trieu
Xu, Kai
Hirao, Hajime
Zhou, Jianrong (Steve)
Keywords: Acyclic Enones
Asymmetric Addition
Issue Date: 2016
Source: Wu, C., Yue, G., Nielsen, C. D.-T., Xu, K., Hirao, H., & Zhou, J. (S.) (2016). Asymmetric Conjugate Addition of Organoboron Reagents to Common Enones Using Copper Catalysts. Journal of the American Chemical Society, 138(3), 742-745.
Series/Report no.: Journal of the American Chemical Society
Abstract: Copper complexes of phosphoramidites efficiently catalyzed asymmetric addition of arylboron reagents to acyclic enones. Importantly, rare 1,4-insertion of arylcopper(I) was identified which led directly to O-bound copper enolates. The new mechanism is fundamentally different from classical oxidative addition/reductive elimination of organocopper(I) on enones.
ISSN: 0002-7863
DOI: 10.1021/jacs.5b11441
Rights: © 2016 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of the American Chemical Society, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [].
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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