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https://hdl.handle.net/10356/89360| Title: | Asymmetric Conjugate Addition of Organoboron Reagents to Common Enones Using Copper Catalysts | Authors: | Wu, Chunlin Yue, Guizhou Nielsen, Christian Duc-Trieu Xu, Kai Hirao, Hajime Zhou, Jianrong (Steve) |
Keywords: | Acyclic Enones Asymmetric Addition |
Issue Date: | 2016 | Source: | Wu, C., Yue, G., Nielsen, C. D.-T., Xu, K., Hirao, H., & Zhou, J. (S.) (2016). Asymmetric Conjugate Addition of Organoboron Reagents to Common Enones Using Copper Catalysts. Journal of the American Chemical Society, 138(3), 742-745. | Series/Report no.: | Journal of the American Chemical Society | Abstract: | Copper complexes of phosphoramidites efficiently catalyzed asymmetric addition of arylboron reagents to acyclic enones. Importantly, rare 1,4-insertion of arylcopper(I) was identified which led directly to O-bound copper enolates. The new mechanism is fundamentally different from classical oxidative addition/reductive elimination of organocopper(I) on enones. | URI: | https://hdl.handle.net/10356/89360 http://hdl.handle.net/10220/44890 |
ISSN: | 0002-7863 | DOI: | 10.1021/jacs.5b11441 | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2016 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of the American Chemical Society, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/jacs.5b11441]. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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| Asymmetric Conjugate Addition of Organoboron Reagents to Common Enones Using Copper Catalysts.pdf | 858.69 kB | Adobe PDF |  View/Open |
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