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Title: Isolation of a cyclic (alkyl)(amino)germylene
Authors: Wang, Liliang
Li, Yongxin
Ganguly, Rakesh
Kinjo, Rei
Lim, Yi Shan
Keywords: Germylene
Low-valent Germanium
Issue Date: 2016
Source: Wang, L., Lim, Y. S., Li, Y., Ganguly, R., & Kinjo, R. (2016). Isolation of a cyclic (alkyl)(amino)germylene. Molecules, 21(8), 990-. doi:10.3390/molecules21080990
Series/Report no.: Molecules
Abstract: A 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC3N five-membered ring skeleton. By reducing 2 with KC8, cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with TEMPO, N2O and S8, producing the 1:2 adduct 4, the oxo-bridged dimer 5 and the sulfido-bridged dimer 6, respectively.
ISSN: 1420-3049
DOI: 10.3390/molecules21080990
Rights: © 2016 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license (
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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