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https://hdl.handle.net/10356/89591| Title: | Isolation of a cyclic (alkyl)(amino)germylene | Authors: | Wang, Liliang Li, Yongxin Ganguly, Rakesh Kinjo, Rei Lim, Yi Shan |
Keywords: | Germylene Low-valent Germanium DRNTU::Science::Chemistry |
Issue Date: | 2016 | Source: | Wang, L., Lim, Y. S., Li, Y., Ganguly, R., & Kinjo, R. (2016). Isolation of a cyclic (alkyl)(amino)germylene. Molecules, 21(8), 990-. doi:10.3390/molecules21080990 | Series/Report no.: | Molecules | Abstract: | A 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC3N five-membered ring skeleton. By reducing 2 with KC8, cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with TEMPO, N2O and S8, producing the 1:2 adduct 4, the oxo-bridged dimer 5 and the sulfido-bridged dimer 6, respectively. | URI: | https://hdl.handle.net/10356/89591 http://hdl.handle.net/10220/46279 |
ISSN: | 1420-3049 | DOI: | 10.3390/molecules21080990 | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2016 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/). | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
| Appears in Collections: | SPMS Journal Articles |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Isolation of a Cyclic (Alkyl)(amino)germylene.pdf | 2.97 MB | Adobe PDF |  View/Open |
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