Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/90280
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dc.contributor.authorLee, Pin-Shengen
dc.contributor.authorXu, Wengangen
dc.contributor.authorYoshikai, Naohikoen
dc.date.accessioned2019-05-30T06:12:14Zen
dc.date.accessioned2019-12-06T17:44:41Z-
dc.date.available2019-05-30T06:12:14Zen
dc.date.available2019-12-06T17:44:41Z-
dc.date.issued2017en
dc.identifier.citationLee, P.-S., Xu, W., & Yoshikai, N. (2017). Directed C–H alkenylation of aryl imines with alkenyl phosphates promoted by a cobalt–N‐heterocyclic carbene catalyst. Advanced Synthesis & Catalysis, 359(24), 4340-4347. doi:10.1002/adsc.201701105en
dc.identifier.issn1615-4150en
dc.identifier.urihttps://hdl.handle.net/10356/90280-
dc.description.abstractWe report herein an ortho‐C–H alkenylation reaction of aryl imines with alkenyl phosphates promoted by a cobalt–N‐heterocyclic carbene (NHC) catalytic system. While commercially available bulky NHC ligands exhibited only modest catalytic activity, elaboration of the nitrogen substituents and backbone of the NHC enabled the desired transformation to proceed in high yield at a mild temperature. The new Co–NHC system proved applicable to a variety of aryl imines and alkenyl phosphates to afford ortho‐alkenylated aryl imines, which serve as precursors to benzofulvene derivatives.en
dc.description.sponsorshipMOE (Min. of Education, S’pore)en
dc.format.extent9 p.en
dc.language.isoenen
dc.relation.ispartofseriesAdvanced Synthesis & Catalysisen
dc.rights© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the peer reviewed version of the following article: Lee, P.-S., Xu, W., & Yoshikai, N. (2017). Directed C–H alkenylation of aryl imines with alkenyl phosphates promoted by a cobalt–N‐heterocyclic carbene catalyst. Advanced Synthesis & Catalysis, 359(24), 4340-4347. doi:10.1002/adsc.201701105, which has been published in final form at http://dx.doi.org/10.1002/adsc.201701105. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.en
dc.subjectC–H Functionalizationen
dc.subjectC–C Bond Formationen
dc.subjectDRNTU::Science::Chemistryen
dc.titleDirected C–H alkenylation of aryl imines with alkenyl phosphates promoted by a cobalt–N‐heterocyclic carbene catalysten
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.identifier.doi10.1002/adsc.201701105en
dc.description.versionAccepted versionen
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item.grantfulltextopen-
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