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DC Field | Value | Language |
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dc.contributor.author | Šolić, Ivan | en |
dc.contributor.author | Seankongsuk, Pattarakiat | en |
dc.contributor.author | Loh, Joanna Kejun | en |
dc.contributor.author | Vilaivan, Tirayut | en |
dc.contributor.author | Bates, Roderick Wayland | en |
dc.date.accessioned | 2019-05-30T02:32:07Z | en |
dc.date.accessioned | 2019-12-06T17:45:11Z | - |
dc.date.available | 2019-05-30T02:32:07Z | en |
dc.date.available | 2019-12-06T17:45:11Z | - |
dc.date.issued | 2017 | en |
dc.identifier.citation | Šolić, I., Seankongsuk, P., Loh, J. K., Vilaivan, T., & Bates, R. W. (2018). Scandium as a pre-catalyst for the deoxygenative allylation of benzylic alcohols. Organic & Biomolecular Chemistry, 16(1), 119-123. doi:10.1039/C7OB02219K | en |
dc.identifier.issn | 1477-0520 | en |
dc.identifier.uri | https://hdl.handle.net/10356/90299 | - |
dc.description.abstract | Scandium triflate is an effective pre-catalyst for the deoxygenative allylation of benzylic alcohols with a narrow substrate window. The reaction is shown to proceed through a “hidden Brønsted acid” mechanism. The reaction is efficient provided that the aryl group is neither too electron rich nor too electron poor. It is shown that this allows useful selectivity. The reaction also works for benzyhydryl alcohols with broader scope. The reaction may also be catalysed by Nafion. | en |
dc.description.sponsorship | ASTAR (Agency for Sci., Tech. and Research, S’pore) | en |
dc.format.extent | 5 p. | en |
dc.language.iso | en | en |
dc.relation.ispartofseries | Organic & Biomolecular Chemistry | en |
dc.rights | © 2018 The Royal Society of Chemistry. All rights reserved. This paper was published in Organic & Biomolecular Chemistry and is made available with permission of The Royal Society of Chemistry. | en |
dc.subject | DRNTU::Science::Chemistry | en |
dc.subject | Allylation | en |
dc.subject | Benzylic Alcohols | en |
dc.title | Scandium as a pre-catalyst for the deoxygenative allylation of benzylic alcohols | en |
dc.type | Journal Article | en |
dc.contributor.school | School of Physical and Mathematical Sciences | en |
dc.identifier.doi | 10.1039/C7OB02219K | en |
dc.description.version | Accepted version | en |
item.fulltext | With Fulltext | - |
item.grantfulltext | open | - |
Appears in Collections: | SPMS Journal Articles |
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File | Description | Size | Format | |
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Scandium as a pre-catalyst for the deoxygenative allylation of benzylic alcohols.pdf | 235.23 kB | Adobe PDF | View/Open |
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