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|Title:||Comprehensive study of ZnO films prepared by filtered cathodic vacuum arc at room temperature||Authors:||Wang, Y. G.
Lau, S. P.
Lee, H. W.
Yu, S. F.
Tay, B. K.
Zhang, X. H.
Tse, K. Y.
Hng, H. H.
|Keywords:||DRNTU::Engineering::Materials::Microelectronics and semiconductor materials::Thin films||Issue Date:||2003||Source:||Wang, Y. G., Lau, S. P., Lee, H. W., Yu, S. F., Tay, B. K., Zhang, X. H. et al. (2003). Comprehensive study of ZnO films prepared by filtered cathodic vacuum arc at room temperature. Journal of applied physics, 94(3), 1597-1604.||Series/Report no.:||Journal of applied physics||Abstract:||Room temperature deposition of high crystal quality zinc oxide (ZnO) films was realized by the filtered cathodic vacuum arc (FCVA) technique. Detrimental macroparticles in the plasma as byproducts of arcing process are removed with an off-plane double bend magnetic filter. The influence of oxygen pressure on the structural, electrical and optical properties of ZnO films were investigated in detail. The crystal structure of ZnO is hexagonal with highly c-axis orientation. Intrinsic stress decreases with an increase of chamber pressure, and near stress-free film was obtained at 1x10-3 Torr. Films with optical transmittance above 90% in the visible range and resistivity as low as 4.1x10-3 Ω cm were prepared at pressure of 5x10-4 Torr. Energetic zinc particles in the cathodic plasma and low substrate temperature enhance the probability of formation of zinc interstitials in the ZnO films. The observation of strong ultraviolet photoluminescence and weak deep level emission at room temperature manifest the high crystal quality of the ZnO films prepared by FCVA. Enlargement of the band gap is observed in the absorption and photoluminescence spectra, the band gap shifts towards lower energy with an increase of oxygen pressure. This phenomenon is attributed to the Burstein–Moss effect.||URI:||https://hdl.handle.net/10356/90403
|DOI:||10.1063/1.1592007||Rights:||© 2003 American Institute of Physics. This paper was published in Journal of Applied Physics and is made available as an electronic reprint (preprint) with permission of American Institute of Physics. The paper can be found at : [DOI: http://dx.doi.org/10.1063/1.1592007]. One print or electronic copy may be made for personal use only. Systematic or multiple reproduction, distribution to multiple locations via electronic or other means, duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper is prohibited and is subject to penalties under law.||Fulltext Permission:||open||Fulltext Availability:||With Fulltext|
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