Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/94407
Title: Surface-induced synthesis and self-assembly of metal suprastructures
Authors: Li, Shaozhou
Huang, Xiao
Li, Hai
Cai, Hui
Gan, Chee Lip
Boey, Freddy Yin Chiang
Zhang, Hua
Keywords: DRNTU::Engineering::Materials
Issue Date: 2010
Source: Li, S., Huang, X., Li, H., Cai, H., Gan, C. L., Boey, F. Y. C., et al. (2010). Surface-induced synthesis and self-assembly of metal suprastructures. Small, 6(23), 2708-2715.
Series/Report no.: Small
Abstract: A systematic study on the synthesis of a series of self-assembled suprastructures, such as cubes, stars, belts, and microspheres, of Ag nanoparticles (AgNPs) in borosilicate glassware heavily cleaned with aqua regia is presented. These self-assembled structures are mostly formed from the crystallographically iso-oriented AgNPs, and exhibit well-defined shapes. In regular washed glassware, only Ag nanowires are synthesized. The formation mechanisms of these self-assembled Ag structures, based on monitoring of their structural evolution in glassware decorated with different molecules, are proposed. This work not only demonstrates that the surface energy of glassware can affect chemical synthesis, but also provides an interesting approach to the shape-controlled synthesis of novel self-assembled suprastructures of AgNPs, which could be potentially used as synthesis templates, drug vessels, and microreactors.
URI: https://hdl.handle.net/10356/94407
http://hdl.handle.net/10220/8577
ISSN: 1613-6829
DOI: 10.1002/smll.201001084
Rights: © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:MSE Journal Articles

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