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Title: Enantioselective oxidative cross-dehydrogenative coupling of tertiary amines to aldehydes
Authors: Zhang, Junmin
Tiwari, Bhoopendra
Xing, Chong
Chen, Xingkuan
Chi, Robin Yonggui
Keywords: DRNTU::Science::Mathematics::Applied mathematics
Issue Date: 2012
Source: Zhang, J., Tiwari, B., Xing, C., Chen, X. & Chi, R. Y. (2012). Enantioselective Oxidative Cross-Dehydrogenative Coupling of Tertiary Amines to Aldehydes. Angewandte Chemie International Edition, 51(15), 3649-3652.
Series/Report no.: Angewandte chemie international edition
Abstract: An enantioselective and direct oxidative coupling of aldehydes to tertiary amines to give β-amino alcohols is described. Catalyzed by copper(II), the reaction proceeds to give a racemic mixture of products; however, by using a combination of copper(II) and a chiral amine catalyst, the reaction gives the desired products with high enantioselectivity.
DOI: 10.1002/anie.201109054
Rights: © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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