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Title: Facile access to chiral ketones through metal-free oxidative C-C bond cleavage of aldehydes by O2
Authors: Tiwari, Bhoopendra
Zhang, Junming
Chi, Robin Yonggui
Keywords: DRNTU::Engineering::Chemical engineering::Biochemical engineering
Issue Date: 2012
Source: Tiwari, B., Zhang, J. & Chi, R. Y. (2012). Facile Access to Chiral Ketones through Metal-Free Oxidative CC Bond Cleavage of Aldehydes by O2. Angewandte Chemie International Edition, 51(8), 1911-1914.
Series/Report no.: Angewandte chemie international edition
Abstract: Giving the metal the boot: The title reaction provides facile access to functionalized chiral ketones from chiral α,α′-disubstituted aldehydes in the presence of molecular oxygen (see scheme). The CC bond-cleavage approach offers an alternative or better method relative to the typical bond-forming strategies used in synthesizing chiral ketones.
DOI: 10.1002/anie.201107473
Rights: © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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