Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/95370
Title: Studies on the magnetic property of μ3-oxotriiron(III) complex [Fe3O(OBz)6(CH3OH)3](NO3)(CH3OH)2 (HOBz-Benzoic acid)
Authors: Wang, Guoxiong
Zhang, Hua
Chen, Yao
Yao, Tianyang
Fu, Degang
Keywords: DRNTU::Engineering::Materials
Issue Date: 1996
Source: Wang, G. X., Zhang, H., Chen, Y., Yao, T. Y., & Fu, D. G. (1996). Studies on the magnetic property of μ3-oxotriiron(III) complex [Fe3O(OBz)6(CH3OH)3](NO3)(CH3OH)2 (HOBz-Benzoic acid). Chinese Journal of Chemistry, 14(3), 200-205.
Series/Report no.: Chinese journal of chemistry
Abstract: The magnetic property of μ3-oxotriiron(III) complex [Fe3O(OBz)6(CH3OH)3](NP3)-(CH3OH)2 (HOBzbenzoic acid) has been studied. We use isosceles triangle model and molecular field correction to fit the experimental magnetic susceptibility data. It shows that an intramolecular antiferromagnetic exchange interaction occurs with J = -31.27 cm−1, J'= -27.26 cm−1, and a weaker intermolecular antiferromagnetic exchange interaction occurs with zJ' = - 3.76 cm−1. We give the d5-d5-d5 energy level diagram of triiron(III) complex as a function of J'/J. From the diagram we can get the total spin ST of the complex as 1/2 in the ground state.
URI: https://hdl.handle.net/10356/95370
http://hdl.handle.net/10220/8570
ISSN: 1001604X
DOI: 10.1002/cjoc.19960140303
Rights: © 1996 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:MSE Journal Articles

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