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Title: Structural evaluation of 6-(10-Mercaptodecoxyl) quinoline self-assembled monolayer on gold by reflectance absorption infrared spectroscopy
Authors: Zhang, Hao-Li
Zhang, Hua
Zhang, Jin
Li, Hu-Lin
Liu, Zhong-Fan
Keywords: DRNTU::Engineering::Materials
Issue Date: 1999
Source: Zhang, H. L., Zhang, H., Zhang, J., Li, H. L., & Liu, Z. F. Structural Evaluation of 6-(10-Mercaptodecoxyl) Quinoline Self-Assembled Monolayer on Gold by Reflectance Absorption Infrared Spectroscopy. Materials Science and Engineering: C, 8-9, 187-190.
Series/Report no.: Materials science and engineering: C
Abstract: Self-assembled monolayer (SAM) of 6-(10-mercaptodecaoxyl)quinoline (MDQ) on gold was characterized by reflectanceabsorptioninfraredspectroscopy (RA-IR). The molecular orientation of MDQ in the SAM was totally evaluated by comparing the RA-IR spectrum of the SAM with a transmission spectrum of a KBr pellet. It was found that the alkyl chain exhibit a tilting angle of 24±5° and a twisting angle of 50±5°. The results suggested that the quinoline moieties in the SAM form an order layer upon the hydrocarbon chain and do not disturb the packing of the alkyl chains obviously.
DOI: 10.1016/S0928-4931(99)00021-1
Rights: © 1999 Elsevier. This is the author created version of a work that has been peer reviewed and accepted for publication by Materials Science and Engineering: C, Elsevier. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [].
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:MSE Journal Articles

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