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Title: One-pot synthesis of carbon-coated SnO2 nanocolloids with improved reversible lithium storage properties
Authors: Archer, Lynden A.
Lou, David Xiong Wen
Chen, Jun Song
Chen, Peng
Keywords: DRNTU::Engineering::Materials
Issue Date: 2009
Source: Lou, D. X. W., Chen, J. S., Chen, P., & Archer, L. A. (2009). One-pot synthesis of carbon-coated SnO2 nanocolloids with improved reversible lithium storage properties. Chemistry of materials, 21(13), 2868-2874.
Series/Report no.: Chemistry of materials
Abstract: We report a simple glucose-mediated hydrothermal method for gram-scale synthesis of nearly monodisperse hybrid SnO2 nanoparticles. Glucose is found to play the dual role of facilitating rapid precipitation of polycrystalline SnO2 nanocolloids and in creating a uniform, glucose-derived, carbon-rich polysaccharide (GCP) coating on the SnO2 nanocores. The thickness of the GCP coating can be facilely manipulated by varying glucose concentration in the synthesis medium. Carbon-coated SnO2 nanocolloids obtained after carbonization of the GCP coating exhibit significantly enhanced cycling performance for lithium storage. Specifically, we find that a capacity of ca. 440 mA h/g can be obtained after more than 100 charge/discharge cycles at a current density of 300 mA/g in hybrid SnO2-carbon electrodes containing as much as 1/3 of their mass in the low-activity carbon shell. By reducing the SnO2-carbon particles with H2, we demonstrate a simple route to carbon-coated Sn nanospheres. Lithium storage properties of the latter materials are also reported. Our results suggest that large initial irreversible losses in these materials are caused not only by the initial, presumably irreversible, reduction of SnO2 as generally perceived in the field, but also by the formation of the solid electrolyte interface (SEI).
DOI: 10.1021/cm900613d
Rights: © 2009 American Chemical Society.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SCBE Journal Articles

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