Switching between halogen- and hydrogen-bonding in stoichiometric variations of a cocrystal of a phosphine oxide

Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/95796

Title:	Switching between halogen- and hydrogen-bonding in stoichiometric variations of a cocrystal of a phosphine oxide
Authors:	Oh, Se Ye. Nickels, Christopher W. Garcia, Felipe. Jones, William. Friščić, Tomislav.
Issue Date:	2012
Source:	Oh, S. Y., Nickels, C. W., Garcia, F., Jones, W., & Friščić, T. (2012). Switching between halogen- and hydrogen-bonding in stoichiometric variations of a cocrystal of a phosphine oxide. CrystEngComm, 14(19), 6110-6114.
Series/Report no.:	CrystEngComm
Abstract:	We describe a two-component cocrystal composition which appears in two stoichiometric variations exhibiting different supramolecular architectures: whereas one stoichiometric variation displays C–HO hydrogen bonds, the second form exhibits short IO halogen bonds alongside Iπ halogen-bonded contacts; the two forms are readily prepared mechanochemically by varying the relative amounts of starting materials in a liquid-assisted grinding process.
URI:	https://hdl.handle.net/10356/95796 http://hdl.handle.net/10220/10826
ISSN:	1466-8033
DOI:	10.1039/c2ce25653c
Schools:	School of Physical and Mathematical Sciences
Rights:	© 2012 The Royal Society of Chemistry.
Fulltext Permission:	none
Fulltext Availability:	No Fulltext
Appears in Collections:	SPMS Journal Articles

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