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Title: Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers
Authors: Jiang, Yaojia
Chan, Wei Chuen
Park, Cheol-Min
Issue Date: 2012
Source: Jiang, Y., Chan, W. C., & Park, C. M. (2012). Expedient Synthesis of Highly Substituted Pyrroles via Tandem Rearrangement of α-Diazo Oxime Ethers. Journal of the American Chemical Society, 134(9), 4104-4107.
Series/Report no.: Journal of the American chemical society
Abstract: An efficient rhodium-catalyzed synthesis of 2H-azirines and pyrroles has been developed. Novel rearrangement of α-oximino ketenes derived from α-diazo oxime ethers provides 2H-azirines bearing quaternary centers and allows for subsequent rearrangement to highly substituted pyrroles in excellent yields.
DOI: 10.1021/ja300552c
Rights: © 2012 American Chemical Society.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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