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|Title:||Co-assembly of Zn(SPh)2 and organic linkers into helical and zig-zag polymer chains||Authors:||Blair, Richard G.
Loo, Say Chye Joachim
|Issue Date:||2012||Source:||Liu, Y., Yu, L., Loo, S. C. J., Blair, R. G., & Zhang, Q. (2012). Co-assembly of Zn(SPh)2 and organic linkers into helical and zig-zag polymer chains. Journal of solid state chemistry, 191, 283-286.||Series/Report no.:||Journal of solid state chemistry||Abstract:||Two novel one-dimensional coordination polymers, single helicate [Zn(SPh)2(TPyTA)(EG)]n (EG=ethylene glycol) (1) and zig-zag structure [Zn(SPh)2(BPyVB)]n (2), were synthesized under solvothermal conditions at 150 °C or room temperature by the co-assembly of Zn(SPh)2 and organic linkers such as 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPyTA) and 1,3-bis(trans-4-pyridylvinyl)benzene (BPyVB). X-ray crystallography study reveals that both polymers 1 and 2 crystallize in space group P21/c of the monoclinic system. The solid-state UV–vis absorption spectra show that 1 and 2 have maxium absorption onsets at 400 nm and 420 nm, respectively. TGA analysis indicates that 1 and 2 are stable up to 110 °C and 210 °C.||URI:||https://hdl.handle.net/10356/95825
|ISSN:||0022-4596||DOI:||10.1016/j.jssc.2012.03.044||Rights:||© 2012 Elsevier Inc.||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||MSE Journal Articles|
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