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Title: Co-assembly of Zn(SPh)2 and organic linkers into helical and zig-zag polymer chains
Authors: Blair, Richard G.
Liu, Yi
Yu, Lingmin
Loo, Say Chye Joachim
Zhang, Qichun
Issue Date: 2012
Source: Liu, Y., Yu, L., Loo, S. C. J., Blair, R. G., & Zhang, Q. (2012). Co-assembly of Zn(SPh)2 and organic linkers into helical and zig-zag polymer chains. Journal of solid state chemistry, 191, 283-286.
Series/Report no.: Journal of solid state chemistry
Abstract: Two novel one-dimensional coordination polymers, single helicate [Zn(SPh)2(TPyTA)(EG)]n (EG=ethylene glycol) (1) and zig-zag structure [Zn(SPh)2(BPyVB)]n (2), were synthesized under solvothermal conditions at 150 °C or room temperature by the co-assembly of Zn(SPh)2 and organic linkers such as 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPyTA) and 1,3-bis(trans-4-pyridylvinyl)benzene (BPyVB). X-ray crystallography study reveals that both polymers 1 and 2 crystallize in space group P21/c of the monoclinic system. The solid-state UV–vis absorption spectra show that 1 and 2 have maxium absorption onsets at 400 nm and 420 nm, respectively. TGA analysis indicates that 1 and 2 are stable up to 110 °C and 210 °C.
ISSN: 0022-4596
DOI: 10.1016/j.jssc.2012.03.044
Rights: © 2012 Elsevier Inc.
Fulltext Permission: none
Fulltext Availability: No Fulltext
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