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https://hdl.handle.net/10356/95853| Title: | C–C bond formation via copper-catalyzed conjugate addition reactions to enones in water at room temperature | Authors: | Isley, Nicholas A. Lipshutz, Bruce H. Huang, Shenlin Leong, Wendy Wen Yi Zhong, Guofu |
Issue Date: | 2012 | Source: | Lipshutz, B. H., Huang, S., Leong, W. W. Y., Zhong, G., & Isley, N. A. (2012). C–C Bond Formation via Copper-Catalyzed Conjugate Addition Reactions to Enones in Water at Room Temperature. Journal of the American Chemical Society, 134(49), 19985-19988. | Series/Report no.: | Journal of the American chemical society | Abstract: | Conjugate addition reactions to enones can now be done in water at room temperature with in situ generated organocopper reagents. Mixing an enone, zinc powder, TMEDA, and an alkyl halide in a micellar environemnt containing catalytic amounts of Cu(I), Ag(I), and Au(III) leads to 1,4-adducts in good isolated yields: no organometallic precursor need be formed. | URI: | https://hdl.handle.net/10356/95853 http://hdl.handle.net/10220/11287 |
DOI: | 10.1021/ja309409e | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2012 American Chemical Society. | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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