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Title: Copper-catalyzed aerobic aliphatic C–H oxygenation directed by an amidine moiety
Authors: Wang, Yi-Feng
Chen, Hui
Zhu, Xu
Chiba, Shunsuke
Issue Date: 2012
Source: Wang, Y. F., Chen, H., Zhu, X., & Chiba, S. (2012). Copper-Catalyzed Aerobic Aliphatic C–H Oxygenation Directed by an Amidine Moiety. Journal of the American Chemical Society, 134(29), 11980-11983.
Series/Report no.: Journal of the American chemical society
Abstract: A method for the oxygenation of tertiary C–H bonds of N-alkylamidines and N-(2-alkylaryl)amidines is described that utilizes the CuBr·SMe2/2,2′-bipyridine catalytic system under an O2 atmosphere and provides dihydrooxazoles and 4H-1,3-benzoxazines. The oxygen atom is incorporated from atmospheric molecular oxygen during the present process.
DOI: 10.1021/ja305833a
Rights: © 2012 American Chemical Society.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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