Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/96088
Title: Mesoporous plasmonic Au-TiO2 nanocomposites for efficient visible-light-driven photocatalytic water reduction
Authors: Fang, Jun
Cao, Shao-Wen
Wang, Zheng
Mohammad Mehdi Shahjamali
Loo, Say Chye Joachim
Barberand, James
Xue, Can
Keywords: DRNTU::Engineering::Materials::Nanostructured materials
Issue Date: 2012
Source: Fang, J., Cao, S. W., Wang, Z., Mohammad, M. S., Loo, S. C. J., Barberand, J. et al. (2012). Mesoporous plasmonic Au-TiO2 nanocomposites for efficient visible-light-driven photocatalytic water reduction. International journal of hydrogen energy. 37(23), 17853–17861.
Series/Report no.: International journal of hydrogen energy
Abstract: The mesoporous Au-TiO2 nanocomposites with different Au concentrations were prepared via a co-polymer assisted sol-gel method. The structures have been characterized by powder X-Ray diffraction, N2 adsorption-desorption isotherms, diffuse reflectance UV-Vis spectroscopy, X-ray photoemission spectroscopy, transmission electron microscopy. Most generated Au nanoparticles were embedded in the mesoporous TiO2 matrix. The prepared Au-TiO2 nanocomposites exhibit remarkable visible-light activity for H2 evolution from photocatalytic water reduction in the presence of ascorbic acid as the electron donor. By comparing with Pt-TiO2 samples, we found that the visible-light activity of the Au-TiO2 nanocomposites could be partially contributed by the defects/impurity states in the TiO2 matrix, while the gold surface plasmons could significantly enhance the weak visible-light excitation of TiO2 matrix. In addition, further studies by controlling irradiation wavelengths suggest that some plasmon-excited electrons could transfer from Au nanoparticles to the contacting TiO2 to reduce water for H2 generation. We believe that these Au-TiO2 nanocomposites as well as the mechanistic studies would have considerable impact on future development of metal-semiconductor hybrid photocatalysts for efficient solar hydrogen production.
URI: https://hdl.handle.net/10356/96088
http://hdl.handle.net/10220/9989
DOI: 10.1016/j.ijhydene.2012.09.023
Rights: © 2012 Hydrogen Energy Publications, LLC. This is the author created version of a work that has been peer reviewed and accepted for publication in International Journal of Hydrogen Energy, published by Elsevier on behalf of Hydrogen Energy Publications, LLC. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document.  The published version is available at: [http://dx.doi.org/10.1016/j.ijhydene.2012.09.023].
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:MSE Journal Articles

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