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|Title:||Direct and stereoselective synthesis of 1,3-cis-3-arylsulphonaminodeoxydisaccharides and oligosaccharides||Authors:||Ding, Feiqing
|Issue Date:||2012||Source:||Ding, F., William, R., Cai, S., Ma, J., & Liu, X.-W. (2012). Direct and Stereoselective Synthesis of 1,3- cis -3- Arylsulphonaminodeoxydisaccharides and Oligosaccharides . The Journal of Organic Chemistry, 77(12), 5245-5254.||Series/Report no.:||The journal of organic chemistry||Abstract:||The 3-aminoglycosides are ubiquitous in biologically important classes of glycoconjugates and naturally occurring oligosaccharides. Despite the rapid growth in the development of synthetic method of 3-amino glycosides, the current state-of-the art suffers from limited substrate scope, low yields, long reaction times, and anomeric mixtures. This work presents a novel direct method for the synthesis of 1,3-cis-3-arylsulphonaminodeoxydisaccharides and oligosaccharides via α-selective glycosylation and hydroamination of glycal in a one-pot manner. This efficient multicomponent reaction methodology provides ready access to 1,3-cis-3-arylsulphonaminodeoxydisaccharides and oligosaccharides and allows derivatization by variation of each component.||URI:||https://hdl.handle.net/10356/96125
|DOI:||10.1021/jo300791v||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||SPMS Journal Articles|
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