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Title: Asymmetric synthesis of enaminophosphines via palladacycle-catalyzed addition of Ph2PH to α,β-unsaturated imines
Authors: Pullarkat, Sumod A.
Huang, Yinhua
Chew, Renta Jonathan
Li, Yongxin
Leung, Pak-Hing
Issue Date: 2012
Source: Huang, Y., Chew, R. J., Pullarkat, S. A., Li, Y., & Leung, P.-H. (2012). Asymmetric Synthesis of Enaminophosphines via Palladacycle-Catalyzed Addition of Ph 2 PH to α,β-Unsaturated Imines . The Journal of Organic Chemistry, 77(16), 6849-6854.
Series/Report no.: The journal of organic chemistry
Abstract: A highly reactive, chemo- and enantioselective addition of diphenylphosphine to α,β-unsaturated imines catalyzed by a palladacycle has been developed, thus providing the access to a series of chiral tertiary enaminophosphines in high yields. A putative catalytic cycle has also been proposed.
DOI: 10.1021/jo300893s
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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