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|Title:||Asymmetric synthesis of enaminophosphines via palladacycle-catalyzed addition of Ph2PH to α,β-unsaturated imines||Authors:||Pullarkat, Sumod A.
Chew, Renta Jonathan
|Issue Date:||2012||Source:||Huang, Y., Chew, R. J., Pullarkat, S. A., Li, Y., & Leung, P.-H. (2012). Asymmetric Synthesis of Enaminophosphines via Palladacycle-Catalyzed Addition of Ph 2 PH to α,β-Unsaturated Imines . The Journal of Organic Chemistry, 77(16), 6849-6854.||Series/Report no.:||The journal of organic chemistry||Abstract:||A highly reactive, chemo- and enantioselective addition of diphenylphosphine to α,β-unsaturated imines catalyzed by a palladacycle has been developed, thus providing the access to a series of chiral tertiary enaminophosphines in high yields. A putative catalytic cycle has also been proposed.||URI:||https://hdl.handle.net/10356/96145
|DOI:||10.1021/jo300893s||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||SPMS Journal Articles|
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