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|Title:||Nickel-complexes with a mixed-donor ligand for photocatalytic hydrogen evolution from aqueous solutions under visible light||Authors:||Han, Jianyu
|Issue Date:||2012||Source:||Han, J., Zhang, W., Zhou, T., Wang, X., & Xu, R. (2012). Nickel-complexes with a mixed-donor ligand for photocatalytic hydrogen evolution from aqueous solutions under visible light. RSC Advances, 2(22), 8293-8296.||Series/Report no.:||RSC advances||Abstract:||Increasing interest has been paid to the development of earth-abundant photocatalyst systems for production of hydrogen from water. In this work, we, for the first time, investigated the photocatalytic activities of complexes formed between β-mecaptoethylamine (L) and Ni(II), NiL2, and the trinuclear complex, Ni(NiL2)22+, with a mixed S and N donor environment. Both complexes were found to be active catalysts for hydrogen evolution in aqueous solutions. In particular, a high quantum efficiency of 30.9 % at 480 nm was obtained over NiL2 when Erythrosin yellowish was used as the photosensitizer.||URI:||https://hdl.handle.net/10356/96152
|ISSN:||2046-2069||DOI:||10.1039/c2ra21422a||Rights:||© 2012 The Royal Society of Chemistry.||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||ERI@N Journal Articles|
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