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Title: Cu–Rh redox relay catalysts for synthesis of azaheterocycles via C–H functionalization
Authors: Chiba, Shunsuke
Issue Date: 2012
Source: Chiba, S. (2012). Cu–Rh Redox Relay Catalysts for Synthesis of Azaheterocycles via C–H Functionalization. Chemistry Letters, 41(12), 1554-1559.
Series/Report no.: Chemistry letters
Abstract: This Highlight Review describes a Cu–Rh bimetallic redox relay catalytic system that enables efficient synthesis of highly substituted isoquinolines and their derivatives from readily available aryl ketoximes or α-arylvinyl azides with internal alkynes via C–H bond functionalization. A preliminary mechanistic investigation revealed that both the Cu and Rh catalysts are prerequisites to achieve the present process, and play their particular roles with synergistic cooperation during the multistep sequence.
DOI: 10.1246/cl.2012.1554
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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