Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/97030
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dc.contributor.authorBaillargeat, Dominiqueen
dc.contributor.authorLi, Hongen
dc.contributor.authorZhang, Qingen
dc.contributor.authorYap, Ray Chin Chongen
dc.contributor.authorTay, Beng Kangen
dc.contributor.authorTeo, Edwin Hang Tongen
dc.contributor.authorOlivier, Aurelienen
dc.date.accessioned2013-06-17T04:16:17Zen
dc.date.accessioned2019-12-06T19:38:04Z-
dc.date.available2013-06-17T04:16:17Zen
dc.date.available2019-12-06T19:38:04Z-
dc.date.copyright2012en
dc.date.issued2012en
dc.identifier.citationLi, H., Zhang, Q., Yap, R. C. C., Tay, B. K., Teo, E. H. T., Olivier, A., et al. (2012). From Bulk to Monolayer MoS2: Evolution of Raman Scattering. Advanced Functional Materials, 22(7), 1385-1390.en
dc.identifier.issn1616-3028en
dc.identifier.urihttps://hdl.handle.net/10356/97030-
dc.description.abstractMolybdenum disulfide (MoS2) is systematically studied using Raman spectroscopy with ultraviolet and visible laser lines. It is shown that only the Raman frequencies of and peaks vary monotonously with the layer number of ultrathin MoS2 flakes, while intensities or widths of the peaks vary arbitrarily. The coupling between electronic transitions and phonons are found to become weaker when the layer number of MoS2 decreases, attributed to the increased electronic transition energies or elongated intralayer atomic bonds in ultrathin MoS2. The asymmetric Raman peak at 454 cm−1, which has been regarded as the overtone of longitudinal optical M phonons in bulk MoS2, is actually a combinational band involving a longitudinal acoustic mode (LA(M)) and an optical mode (). Our findings suggest a clear evolution of the coupling between electronic transition and phonon when MoS2 is scaled down from three- to two-dimensional geometry.en
dc.language.isoenen
dc.relation.ispartofseriesAdvanced functional materialsen
dc.rights© 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.en
dc.subjectDRNTU::Engineering::Electrical and electronic engineeringen
dc.titleFrom bulk to monolayer MoS2 : evolution of Raman scatteringen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Electrical and Electronic Engineeringen
dc.contributor.researchResearch Techno Plazaen
dc.identifier.doi10.1002/adfm.201102111en
item.grantfulltextnone-
item.fulltextNo Fulltext-
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