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Title: From bulk to monolayer MoS2 : evolution of Raman scattering
Authors: Baillargeat, Dominique
Li, Hong
Zhang, Qing
Yap, Ray Chin Chong
Tay, Beng Kang
Teo, Edwin Hang Tong
Olivier, Aurelien
Keywords: DRNTU::Engineering::Electrical and electronic engineering
Issue Date: 2012
Source: Li, H., Zhang, Q., Yap, R. C. C., Tay, B. K., Teo, E. H. T., Olivier, A., et al. (2012). From Bulk to Monolayer MoS2: Evolution of Raman Scattering. Advanced Functional Materials, 22(7), 1385-1390.
Series/Report no.: Advanced functional materials
Abstract: Molybdenum disulfide (MoS2) is systematically studied using Raman spectroscopy with ultraviolet and visible laser lines. It is shown that only the Raman frequencies of and peaks vary monotonously with the layer number of ultrathin MoS2 flakes, while intensities or widths of the peaks vary arbitrarily. The coupling between electronic transitions and phonons are found to become weaker when the layer number of MoS2 decreases, attributed to the increased electronic transition energies or elongated intralayer atomic bonds in ultrathin MoS2. The asymmetric Raman peak at 454 cm−1, which has been regarded as the overtone of longitudinal optical M phonons in bulk MoS2, is actually a combinational band involving a longitudinal acoustic mode (LA(M)) and an optical mode (). Our findings suggest a clear evolution of the coupling between electronic transition and phonon when MoS2 is scaled down from three- to two-dimensional geometry.
ISSN: 1616-3028
DOI: 10.1002/adfm.201102111
Rights: © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:EEE Journal Articles

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