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https://hdl.handle.net/10356/97105
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Zhang, Feng-Lian | en |
dc.contributor.author | Wang, Yi-Feng | en |
dc.contributor.author | Lonca, Geoffroy Hervé | en |
dc.contributor.author | Zhu, Xu | en |
dc.contributor.author | Chiba, Shunsuke | en |
dc.date.accessioned | 2014-06-11T03:09:39Z | en |
dc.date.accessioned | 2019-12-06T19:38:59Z | - |
dc.date.available | 2014-06-11T03:09:39Z | en |
dc.date.available | 2019-12-06T19:38:59Z | - |
dc.date.copyright | 2014 | en |
dc.date.issued | 2014 | en |
dc.identifier.citation | Zhang, F.-L., Wang, Y.-F., Lonca, G. H., Zhu, X., & Chiba, S. (2014). Amide Synthesis by Nucleophilic Attack of Vinyl Azides. Angewandte Chemie International Edition, 53(17), 4390-4394. | en |
dc.identifier.issn | 1433-7851 | en |
dc.identifier.uri | https://hdl.handle.net/10356/97105 | - |
dc.description.abstract | A method for the synthesis of amide-containing molecules was developed using vinyl azides as an enamine-type nucleophile towards carbon electrophiles, such as imines, aldehydes, and carbocations that were generated from alcohols in the presence of BF3⋅OEt2. After nucleophilic attack of the vinyl azide, a substituent of the resulting iminodiazonium ion intermediate migrates to form a nitrilium ion, which is hydrolyzed to afford the corresponding amide. | en |
dc.language.iso | en | en |
dc.relation.ispartofseries | Angewandte chemie international edition | en |
dc.rights | © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | en |
dc.subject | DRNTU::Science::Chemistry::Inorganic chemistry::Synthesis | en |
dc.title | Amide synthesis by nucleophilic attack of vinyl azides | en |
dc.type | Journal Article | en |
dc.contributor.school | School of Physical and Mathematical Sciences | en |
dc.identifier.doi | 10.1002/anie.201400938 | en |
item.grantfulltext | none | - |
item.fulltext | No Fulltext | - |
Appears in Collections: | SPMS Journal Articles |
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