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Title: Enantioselective activation of stable carboxylate esters as enolate equivalents via N-heterocyclic carbene catalysts
Authors: Hao, Lin
Du, Yu
Lv, Hui
Chen, Xingkuan
Jiang, Huishen
Shao, Yaling
Chi, Robin Yonggui
Issue Date: 2012
Source: Hao, L., Du, Y., Lv, H., Chen, X., Jiang, H., Shao, Y., et al. (2012). Enantioselective Activation of Stable Carboxylate Esters as Enolate Equivalents via N-Heterocyclic Carbene Catalysts. Organic Letters, 14(8), 2154-2157.
Series/Report no.: Organic letters
Abstract: The first N-Heterocyclic Carbene (NHC) mediated activation of stable carboxylate esters to generate enolate intermediates is disclosed. The catalytically generated arylacetic ester enolates undergo enantioselective reactions with α,β-unsaturated imines.
ISSN: 1523-7060
DOI: 10.1021/ol300676w
Rights: © 2012 American Chemical Society.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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