Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/97360
Title: Selective catalytic sp3 C–O bond cleavage with C–N bond formation in 3-alkoxy-1-propanols
Authors: Chen, Cheng
Hong, Soon Hyeok
Issue Date: 2012
Source: Chen, C., & Hong, S. H. (2012). Selective Catalytic sp3 C–O Bond Cleavage with C–N Bond Formation in 3-Alkoxy-1-propanols. Organic Letters, 14(12), 2992-2995.
Series/Report no.: Organic letters
Abstract: The ruthenium catalyzed selective sp3 C–O cleavage with amide formation was reported in reactions of 3-alkoxy-1-propanol derivatives and amines. The cleavage only occurs at the C3–O position even with 3-benzyloxy-1-propanol. Based on the experimental results, O-bound and C-bound Ru enolate complexes were proposed as key intermediates for the unique selective sp3 C–O bond cleavage in 3-alkoxy-1-propanols.
URI: https://hdl.handle.net/10356/97360
http://hdl.handle.net/10220/10607
ISSN: 1523-7060
DOI: 10.1021/ol3009842
Rights: © 2012 American Chemical Society.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

SCOPUSTM   
Citations 10

27
Updated on Jan 18, 2023

Web of ScienceTM
Citations 10

28
Updated on Jan 24, 2023

Page view(s) 50

469
Updated on Jan 28, 2023

Google ScholarTM

Check

Altmetric


Plumx

Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.