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Title: Selective catalytic sp3 C–O bond cleavage with C–N bond formation in 3-alkoxy-1-propanols
Authors: Chen, Cheng
Hong, Soon Hyeok
Issue Date: 2012
Source: Chen, C., & Hong, S. H. (2012). Selective Catalytic sp3 C–O Bond Cleavage with C–N Bond Formation in 3-Alkoxy-1-propanols. Organic Letters, 14(12), 2992-2995.
Series/Report no.: Organic letters
Abstract: The ruthenium catalyzed selective sp3 C–O cleavage with amide formation was reported in reactions of 3-alkoxy-1-propanol derivatives and amines. The cleavage only occurs at the C3–O position even with 3-benzyloxy-1-propanol. Based on the experimental results, O-bound and C-bound Ru enolate complexes were proposed as key intermediates for the unique selective sp3 C–O bond cleavage in 3-alkoxy-1-propanols.
ISSN: 1523-7060
DOI: 10.1021/ol3009842
Rights: © 2012 American Chemical Society.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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