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https://hdl.handle.net/10356/97360| Title: | Selective catalytic sp3 C–O bond cleavage with C–N bond formation in 3-alkoxy-1-propanols | Authors: | Chen, Cheng Hong, Soon Hyeok |
Issue Date: | 2012 | Source: | Chen, C., & Hong, S. H. (2012). Selective Catalytic sp3 C–O Bond Cleavage with C–N Bond Formation in 3-Alkoxy-1-propanols. Organic Letters, 14(12), 2992-2995. | Series/Report no.: | Organic letters | Abstract: | The ruthenium catalyzed selective sp3 C–O cleavage with amide formation was reported in reactions of 3-alkoxy-1-propanol derivatives and amines. The cleavage only occurs at the C3–O position even with 3-benzyloxy-1-propanol. Based on the experimental results, O-bound and C-bound Ru enolate complexes were proposed as key intermediates for the unique selective sp3 C–O bond cleavage in 3-alkoxy-1-propanols. | URI: | https://hdl.handle.net/10356/97360 http://hdl.handle.net/10220/10607 |
ISSN: | 1523-7060 | DOI: | 10.1021/ol3009842 | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2012 American Chemical Society. | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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