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https://hdl.handle.net/10356/97375| Title: | β-type glycosidic bond formation by palladium-catalyzed decarboxylative allylation | Authors: | Xiang, Shaohua Lu, Zhiqiang He, Jingxi MaiHoang, Kim Le Zeng, Jing Liu, Xue-Wei |
Keywords: | DRNTU::Science::Chemistry::Organic chemistry::Carbanions | Issue Date: | 2013 | Source: | Xiang, S., Lu, Z., He, J., MaiHoang, K. L., Zeng, J., & Liu, X. W. (2013). β-type glycosidic bond formation by palladium-catalyzed decarboxylative allylation. Chemistry - a European journal, 19(42), 14047-14051. | Series/Report no.: | Chemistry - a European journal | Abstract: | Decarboxylative allylation of glycals: A β-type glycosidic bond has been constructed in high regio- and stereoselectivity by means of a palladium-catalyzed decarboxylative O-glycosylation. Various kinds of glycals with different protecting groups have been examined for this reaction to afford a diverse set of glycosylated products, including phenolic O-glycosides, thiophenolic S-glycoside, aliphatic O-glycosides, and disaccharides with excellent β-selectivity and reasonable to excellent yields. | URI: | https://hdl.handle.net/10356/97375 http://hdl.handle.net/10220/25639 |
ISSN: | 0947-6539 | DOI: | 10.1002/chem.201303241 | Rights: | © 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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