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Title: β-type glycosidic bond formation by palladium-catalyzed decarboxylative allylation
Authors: Xiang, Shaohua
Lu, Zhiqiang
He, Jingxi
MaiHoang, Kim Le
Zeng, Jing
Liu, Xue-Wei
Keywords: DRNTU::Science::Chemistry::Organic chemistry::Carbanions
Issue Date: 2013
Source: Xiang, S., Lu, Z., He, J., MaiHoang, K. L., Zeng, J., & Liu, X. W. (2013). β-type glycosidic bond formation by palladium-catalyzed decarboxylative allylation. Chemistry - a European journal, 19(42), 14047-14051.
Series/Report no.: Chemistry - a European journal
Abstract: Decarboxylative allylation of glycals: A β-type glycosidic bond has been constructed in high regio- and stereoselectivity by means of a palladium-catalyzed decarboxylative O-glycosylation. Various kinds of glycals with different protecting groups have been examined for this reaction to afford a diverse set of glycosylated products, including phenolic O-glycosides, thiophenolic S-glycoside, aliphatic O-glycosides, and disaccharides with excellent β-selectivity and reasonable to excellent yields.
ISSN: 0947-6539
DOI: 10.1002/chem.201303241
Rights: © 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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