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https://hdl.handle.net/10356/97651| Title: | Oxidative γ-addition of enals to trifluoromethyl ketones : enantioselectivity control via Lewis acid/N-heterocyclic carbene cooperative catalysis | Authors: | Mo, Junming Chen, Xingkuan Chi, Robin Yonggui |
Issue Date: | 2012 | Source: | Mo, J., Chen, X., & Chi, Y. R. (2012). Oxidative γ-Addition of Enals to Trifluoromethyl Ketones: Enantioselectivity Control via Lewis Acid/N-Heterocyclic Carbene Cooperative Catalysis. Journal of the American Chemical Society, 134(21), 8810-8813. | Series/Report no.: | Journal of the American chemical society | Abstract: | An oxidative γ-functionalization of enals under N-heterocyclic carbene (NHC) catalysis to give unsaturated δ-lactones is disclosed. Enantioselectivity control involving the relatively remote enal γ-carbon was achieved via Lewis acid [Sc(OTf)3 or combined Sc(OTf)3/Mg(OTf)2] and NHC cooperative catalysis. | URI: | https://hdl.handle.net/10356/97651 http://hdl.handle.net/10220/11248 |
DOI: | 10.1021/ja303618z | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2012 American Chemical Society. | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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