Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/98420
Title: 2,2′-biphospholes : building blocks for tuning the HOMO-LUMO gap of π-systems using covalent bonding and metal coordination
Authors: Chen, Hui
Delaunay, Wylliam
Yu, Liujian
Joly, Damien
Wang, Zuoyong
Li, Jin
Wang, Zisu
Lescop, Christophe
Tondelier, Denis
Geffroy, Bernard
Duan, Zheng
Hissler, Muriel
Mathey, François
Réau, Régis
Issue Date: 2012
Source: Chen, H., Delaunay, W., Yu, L., Joly, D., Wang, Z., Li, J., et al. (2012). 2,2′-Biphospholes: Building Blocks for Tuning the HOMO-LUMO Gap of π-Systems Using Covalent Bonding and Metal Coordination. Angewandte Chemie International Edition, 51(1), 214-217.
Series/Report no.: Angewandte chemie international edition
Abstract: A new angle: The insertion of a 2,2′-biphosphole subunit into π-conjugated systems offers a new way to control the HOMO–LUMO gap. Tuning of the dihedral angle (θ) between the two phosphorous heterocycles, either by metal coordination or covalent bonding through the P substitution can lead to control of the band gap. These new π-conjugated systems can be used as emitting materials in white organic light-emitting devices (WOLEDs).
URI: https://hdl.handle.net/10356/98420
http://hdl.handle.net/10220/12464
ISSN: 1433-7851
DOI: 10.1002/anie.201105924
Schools: School of Physical and Mathematical Sciences 
Rights: © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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