Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/98442
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dc.contributor.authorZhang, Wenen
dc.contributor.authorTan, Davinen
dc.contributor.authorLee, Richmonden
dc.contributor.authorTong, Guanghuen
dc.contributor.authorChen, Wenchaoen
dc.contributor.authorQi, Baojianen
dc.contributor.authorHuang, Kuo-Weien
dc.contributor.authorTan, Choon-Hongen
dc.contributor.authorJiang, Zhiyongen
dc.date.accessioned2013-07-29T06:23:52Zen
dc.date.accessioned2019-12-06T19:55:16Z-
dc.date.available2013-07-29T06:23:52Zen
dc.date.available2019-12-06T19:55:16Z-
dc.date.copyright2012en
dc.date.issued2012en
dc.identifier.citationZhang, W., Tan, D., Lee, R., Tong, G., Chen, W., Qi, B., et al(2012). Highly Enantio- and Diastereoselective Reactions of γ-Substituted Butenolides Through Direct Vinylogous Conjugate Additions. Angewandte Chemie International Edition, 51(40), 10069-10073.en
dc.identifier.issn1433-7851en
dc.identifier.urihttps://hdl.handle.net/10356/98442-
dc.identifier.urihttp://hdl.handle.net/10220/12455en
dc.description.abstractThe strength of the weak: An L-tert-leucine-derived amine–thiourea catalyst (see scheme, green box) promotes the asymmetric vinylogous conjugate addition reaction between γ-aryl- and alkyl-substituted butenolides with the butenamides and enoates shown. Computational studies show the preference for the observed stereochemistry is a result of favourable weak non-bonding interactions, which stabilize the transition state.en
dc.language.isoenen
dc.relation.ispartofseriesAngewandte chemie international editionen
dc.rights© 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.en
dc.subjectDRNTU::Science::Chemistryen
dc.titleHighly enantio- and diastereoselective reactions of γ-substituted butenolides through direct vinylogous conjugate additionsen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.identifier.doi10.1002/anie.201205872en
item.fulltextNo Fulltext-
item.grantfulltextnone-
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