Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/98671
Title: The original coordination chemistry of 2-phosphaphenol with copper(I) and gold(I) halides
Authors: Mao, Yanli
Lim, Kelvin Meng Hui
Li, Yongxin
Ganguly, Rakesh
Mathey, François
Issue Date: 2013
Source: Mao, Y., Lim, K. M. H., Li, Y., Ganguly, R., & Mathey, F. (2013). The Original Coordination Chemistry of 2-Phosphaphenol with Copper(I) and Gold(I) Halides. Organometallics, 32(12), 3562-3565.
Series/Report no.: Organometallics
Abstract: 2-Phosphaphenol (L) forms unusual complexes with copper and gold halides. With CuCl, a dimeric [L2CuCl]2 complex is observed with L acting both as η1-P terminal and μ2-P bridging ligand and a copper–copper short contact of 2.549 Å. With copper bromide, a distorted infinite chain [L2CuBr]n is formed, whereas with copper iodide, the zigzag chain [L2CuI]n is observed. The phosphaphenol acts as a terminal ligand coating the CuX molecular wires. With gold chloride, a dimeric [LAuCl]2 complex is formed, which is held by an aurophilic interaction at 3.132 Å.
URI: https://hdl.handle.net/10356/98671
http://hdl.handle.net/10220/17365
DOI: 10.1021/om400207y
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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