Please use this identifier to cite or link to this item:
Title: The original coordination chemistry of 2-phosphaphenol with copper(I) and gold(I) halides
Authors: Mao, Yanli
Lim, Kelvin Meng Hui
Li, Yongxin
Ganguly, Rakesh
Mathey, François
Issue Date: 2013
Source: Mao, Y., Lim, K. M. H., Li, Y., Ganguly, R., & Mathey, F. (2013). The Original Coordination Chemistry of 2-Phosphaphenol with Copper(I) and Gold(I) Halides. Organometallics, 32(12), 3562-3565.
Series/Report no.: Organometallics
Abstract: 2-Phosphaphenol (L) forms unusual complexes with copper and gold halides. With CuCl, a dimeric [L2CuCl]2 complex is observed with L acting both as η1-P terminal and μ2-P bridging ligand and a copper–copper short contact of 2.549 Å. With copper bromide, a distorted infinite chain [L2CuBr]n is formed, whereas with copper iodide, the zigzag chain [L2CuI]n is observed. The phosphaphenol acts as a terminal ligand coating the CuX molecular wires. With gold chloride, a dimeric [LAuCl]2 complex is formed, which is held by an aurophilic interaction at 3.132 Å.
DOI: 10.1021/om400207y
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

Citations 10

Updated on Nov 28, 2022

Web of ScienceTM
Citations 10

Updated on Nov 25, 2022

Page view(s) 20

Updated on Nov 29, 2022

Google ScholarTM




Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.