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Title: A family of metal-organic frameworks exhibiting size-selective catalysis with encapsulated noble-metal nanoparticles
Authors: Zhang, Weina
Lu, Guang
Cui, Chenlong
Liu, Yayuan
Li, Shaozhou
Yan, Wenjin
Xing, Chong
Chi, Robin Yonggui
Yang, Yanhui
Huo, Fengwei
Keywords: DRNTU::Engineering::Chemical engineering::Chemical processes
Issue Date: 2014
Source: Zhang, W., Lu, G., Cui, C., Liu, Y., Li, S., Yan, W., et al. (2014). A Family of Metal-Organic Frameworks Exhibiting Size-Selective Catalysis with Encapsulated Noble-Metal Nanoparticles. Advanced Materials, in press.
Series/Report no.: Advanced materials
Abstract: The encapsulation of noble-metal nanoparticles (NPs) in metal-organic frameworks (MOFs) with carboxylic acid ligands, the most extensive branch of the MOF family, gives NP/MOF composites that exhibit excellent shape-selective catalytic performance in olefin hydrogenation, aqueous reaction in the reduction of 4-nitrophenol, and faster molecular diffusion in CO oxidation. The strategy of using functionalized cavities of MOFs as hosts for different metal NPs looks promising for the development of high-performance heterogeneous catalysts.
ISSN: 0935-9648
DOI: 10.1002/adma.201400620
Rights: © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:MSE Journal Articles
SCBE Journal Articles
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