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Title: Asymmetric syntheses of 8-oxabicyclo[3,2,1]octanes : a cationic cascade cyclization
Authors: Li, Bin
Zhao, Yu-Jun
Lai, Yin-Chang
Loh, Teck-Peng
Issue Date: 2012
Source: Li, B., Zhao, Y.-J., Lai, Y.-C., & Loh, T.-P. (2012). Asymmetric Syntheses of 8-Oxabicyclo[3,2,1]octanes: A Cationic Cascade Cyclization. Angewandte Chemie International Edition, 51(32), 8041-8045.
Series/Report no.: Angewandte chemie international edition
Abstract: High octane: A novel and practical syntheses of 8-oxabicyclo[3.2.1]octanes using a cationic cascade cyclization reaction has been developed (see scheme; TIPS=triisopropylsilyl). The diastereomer of the cyclization product isolated depends upon whether the acetal or aldehyde substrate is used.
ISSN: 1433-7851
DOI: 10.1002/anie.201202699
Rights: © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
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