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Title: A new type of phosphaferrocene–pyrrole–phosphaferrocene P-N-P pincer ligand
Authors: Tian, Rongqiang
Ng, Yongxiang
Ganguly, Rakesh
Mathey, François
Keywords: DRNTU::Science::Chemistry
Issue Date: 2012
Source: Tian, R., Ng, Y., Ganguly, R., & Mathey, F. (2012). A new type of phosphaferrocene–pyrrole–phosphaferrocene P-N-P pincer ligand. Organometallics, 31(6), 2486-2488.
Series/Report no.: Organometallics
Abstract: A 2-ethoxycarbonylphosphaferrocene was reduced to the corresponding 2-hydroxymethyl derivative, which was condensed with pyrrole in a 2:1 ratio in the presence of BF3 to give a phosphaferrocene–pyrrole–phosphaferrocene pincer ligand. This tridentate ligand, in turn, reacted with [Rh(acac)(CO)2] to yield a rhodium carbonyl pincer complex. This complex was characterized by X-ray crystal structure analysis and tested in the hydroformylation of internal olefins.
DOI: 10.1021/om300061d
Fulltext Permission: none
Fulltext Availability: No Fulltext
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