Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/99502
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dc.contributor.authorChua, Chun Kiangen
dc.contributor.authorSofer, Zdeněken
dc.contributor.authorPumera, Martinen
dc.date.accessioned2013-08-06T03:12:27Zen
dc.date.accessioned2019-12-06T20:08:08Z-
dc.date.available2013-08-06T03:12:27Zen
dc.date.available2019-12-06T20:08:08Z-
dc.date.copyright2012en
dc.date.issued2012en
dc.identifier.citationChua, C. K., Sofer, Z.,& Pumera, M. (2012). Graphite Oxides: Effects of Permanganate and Chlorate Oxidants on the Oxygen Composition. Chemistry - A European Journal, 18(42), 13453-13459.en
dc.identifier.issn0947-6539en
dc.identifier.urihttps://hdl.handle.net/10356/99502-
dc.description.abstractResearch on graphene materials has refocused on graphite oxides (GOs) in recent years. The fabrication of GO is commonly accomplished by using concentrated sulfuric acid in conjunction with: a) fuming nitric acid and KClO3 oxidant (Staudenmaier); b) concentrated nitric acid and KClO3 oxidant (Hofmann); c) sodium nitrate for in situ production of nitric acid in the presence of KMnO4 (Hummers); or d) concentrated phosphoric acid with KMnO4 (Tour). These methods have been used interchangeably in the graphene community, since the properties of GOs produced by these different methods were assumed as almost similar. In light of the wide applicability of GOs in nanotechnology applications, in which presence of certain oxygen functional groups are specifically important, the qualities and functionalities of the GOs produced by using these four different methods, side-by-side, was investigated. The structural characterizations of the GOs would be probed by using high resolution X-ray photoelectron spectroscopy, nuclear magnetic resonance, Fourier transform infrared spectroscopy, and Raman spectroscopy. Further electrochemical applicability would be evaluated by using electrochemical impedance spectroscopy and cyclic voltammetry techniques. Our analyses highlighted that the oxidation methods based on permanganate oxidant (Hummers and Tour methods) gave GOs with lower heterogeneous electron-transfer rates and a higher amount of carbonyl and carboxyl functionalities compared with when using chlorate oxidant (Staudenmaier and Hofmann methods). These observations indicated large disparities between the GOs obtained from different oxidation methods. Such insights would provide fundamental knowledge for fine tuning GO for future applications.en
dc.language.isoenen
dc.relation.ispartofseriesChemistry - a European journalen
dc.titleGraphite oxides : effects of permanganate and chlorate oxidants on the oxygen compositionen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.identifier.doi10.1002/chem.201202320en
item.fulltextNo Fulltext-
item.grantfulltextnone-
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