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Title: N-heterocyclic carbene catalyzed homoenolate-addition reaction of enals and nitroalkenes : asymmetric synthesis of 5-carbon-synthon δ-nitroesters
Authors: Maji, Biswajit
Ji, Li
Wang, Siming
Vedachalam, Seenuvasan
Ganguly, Rakesh
Liu, Xue-Wei
Keywords: DRNTU::Science::Chemistry
Issue Date: 2012
Source: Maji, B., Ji, L., Wang, S., Vedachalam, S., Ganguly, R., & Liu, X.-W. (2012). N-Heterocyclic Carbene Catalyzed Homoenolate-Addition Reaction of Enals and Nitroalkenes: Asymmetric Synthesis of 5-Carbon-Synthon δ-Nitroesters. Angewandte Chemie International Edition, 51(33), 8276-8280.
Series/Report no.: Angewandte chemie international edition
Abstract: Synthesizing synthons: The highly enantioselective title reaction is described. It employs catalytic amounts of N-heterocyclic carbene precursors and transforms a broad range of nitroalkenes, such as nitrodienes, nitroenynes, and nitrostyrenes, through reaction with a broad range of enals, into δ-nitroesters via homoenolate intermediates (see scheme).
ISSN: 1433-7851
DOI: 10.1002/anie.201203449
Rights: © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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