Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/99588
Full metadata record
DC FieldValueLanguage
dc.contributor.authorYamakawa, Takeshien
dc.contributor.authorYoshikai, Naohikoen
dc.date.accessioned2013-11-08T06:00:56Zen
dc.date.accessioned2019-12-06T20:09:17Z-
dc.date.available2013-11-08T06:00:56Zen
dc.date.available2019-12-06T20:09:17Z-
dc.date.copyright2013en
dc.date.issued2013en
dc.identifier.citationYamakawa, T., & Yoshikai, N. (2013). Cobalt-catalyzed ortho-alkenylation of aromatic aldimines via chelation-assisted C–H bond activation. Tetrahedron, 69(22), 4459-4465en
dc.identifier.issn0040-4020en
dc.identifier.urihttps://hdl.handle.net/10356/99588-
dc.identifier.urihttp://hdl.handle.net/10220/17467en
dc.description.abstractAn ortho-alkenylation reaction of an aromatic aldimine with an internal alkyne is efficiently promoted by a cobalt catalyst generated from CoBr2, triarylphosphine, and iPrMgBr. The reaction takes place under mild room-temperature conditions to afford, upon acidic hydrolysis, a variety of ortho-alkenylated aromatic aldehydes in moderate to excellent yields. The neighboring formyl and alkenyl groups in the product can be utilized as synthetic handles for the facile construction of indene and naphthalene carbocycles.en
dc.language.isoenen
dc.relation.ispartofseriesTetrahedronen
dc.subjectDRNTU::Science::Chemistry::Organic chemistryen
dc.titleCobalt-catalyzed ortho-alkenylation of aromatic aldimines via chelation-assisted C–H bond activationen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.identifier.doihttp://dx.doi.org/10.1016/j.tet.2013.02.092en
item.grantfulltextnone-
item.fulltextNo Fulltext-
Appears in Collections:SPMS Journal Articles

Google ScholarTM

Check

Altmetric

Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.