Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/99720
Title: Generation and reactivity of methylphosphaketene in the coordination sphere of tungsten
Authors: Mao, Yanli
Wang, Zhiyue
Ganguly, Rakesh
Mathey, François
Keywords: DRNTU::Science::Chemistry
Issue Date: 2012
Source: Mao, Y., Wang, Z., Ganguly, R., & Mathey, F. (2012). Generation and reactivity of methylphosphaketene in the coordination sphere of tungsten. Organometallics, 31(13), 4786-4790.
Series/Report no.: Organometallics
Abstract: The [4 + 2] cycloadduct between the 1-methyl-2-keto-1,2-dihydrophosphinine pentacarbonyltungsten complex and dimethyl acetylenedicarboxylate can be used as a precursor for the methylphosphaketene tungsten complex under UV irradiation at room temperature. Under these conditions, the phosphaketene complex easily loses CO to give the methylphosphinidene complex. Highly reactive alcohols and primary alkylamines trap both the phosphaketene and the phosphinidene complexes. Less reactive phenol and bulky amines together with alkynes and conjugated dienes only trap the phosphinidene complex.
URI: https://hdl.handle.net/10356/99720
http://hdl.handle.net/10220/13709
DOI: 10.1021/om300333v
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

SCOPUSTM   
Citations 20

10
Updated on Nov 18, 2022

Web of ScienceTM
Citations 20

10
Updated on Nov 28, 2022

Page view(s) 50

529
Updated on Dec 1, 2022

Google ScholarTM

Check

Altmetric


Plumx

Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.