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Title: “Clean reaction” strategy to approach a stable, green Heptatwistacene containing a single terminal pyrene unit
Authors: Malliakas, Christos D.
Kanatzidis, Mercouri G.
Xiao, Jinchong
Liu, Yi
Zhou, Feng
Li, Gang
Su, Haibin
Wudl, Fred
Zhang, Qichun
Issue Date: 2012
Source: Xiao, J., Malliakas, C. D., Liu, Y., Zhou, F., Li, G., Su, H., Kanatzidis, M. G., Wudl, F.,& Zhang, Q. (2012). “Clean Reaction” Strategy to Approach a Stable, Green Heptatwistacene Containing a Single Terminal Pyrene Unit. Chemistry - An Asian Journal, 7(4), 672-675.
Series/Report no.: Chemistry - an Asian journal
Abstract: Let's twist again: A “clean reaction” strategy based on thermally eliminating lactam bridges from a soluble acene precursor through a retro-Diels–Alder reaction gives a new, stable, green heptatwistacene (see structure). The molecule has a twist angle of 23.49°, is very stable even in air, and has an optical band gap of 1.82 eV.
ISSN: 1861-4728
DOI: 10.1002/asia.201100910
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:MSE Journal Articles

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