Now showing items 1-1 of 1

    • Reaction of terminal phosphinidene complexes with dihydrogen 

      Duffy, Matthew P.; Ting, Liow Yu; Nicholls, Leo; Li, Yongxin; Ganguly, Rakesh; Mathey, François (2011)
      The reaction of H2 with [RP-W(CO)5] (R = Ph, Me) above 120 °C leads, first, to the secondary diphosphine complex (RPH-PHR)(W(CO)5)2 and then to the primary phosphine complex (RPH2)(W(CO)5). On the basis of DFT calculations, ...