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Group II metal complexes of the germylidendiide dianion radical and germylidenide anion
The two-electron reduction of a Group 14-element(I) complex [RË⋅] (E=Ge, R=supporting ligand) to form a novel low-valent dianion radical with the composition [RË:]. 2− is reported. The reaction of [LGeCl] (1, L=2,6-(CH[DOUBLE ...
Zwitterionic base-stabilized digermadistannacyclobutadiene and tetragermacyclobutadiene
The syntheses of a zwitterionic base-stabilized digermadistannacyclobutadiene and tetragermacyclobutadiene supported by amidinates and low-valent germanium amidinate substituents are described. The reaction of the amidinate ...