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In situ formation of new organic ligands to construct two novel self-charge-transfer Pb(ii)-based frameworks
Employing in situ-formed new organic ligands, two Pb(II)-based metal–organic frameworks were synthesized. Compound 1 possesses a 3D framework while compound 2 has a layered structure. Solid state UV-visible absorptions ...
Synthesis, crystal structure, and optical properties of a three-dimensional quaternary Hg–In–S–Cl chalcohalide : Hg7InS6Cl5
A crystalline three-dimensional (3D) quaternary chalcohalide, Hg7InS6Cl5 (1), has been synthesized through a solid-state reaction under medium temperature. It is the first example in the family of the Hg–IIIA–Q–X (Q = S, ...